Activation and Functionalization of C—H Bonds - download pdf or read online

By Karen I. Goldberg and Alan S. Goldman (Eds.)

ISBN-10: 0841219915

ISBN-13: 9780841219915

ISBN-10: 0841238499

ISBN-13: 9780841238497

Content material: 1. Organometallic C-H bond activation : an advent / Alan S. Goldman and Karen I. Goldberg -- 2. C-H bond activation through iridium and rhodium complexes : catalytic hydrogen-deuterium alternate and C-C bond-forming reactions / Steven R. Klei, Kian L. Tan, Jeffrey T. Golden, Cathleen M. Yung, Reema ok. Thalji, Kateri A. Ahrendt, Jonathan A. Ellman, T. Don Tilley and Robert G. Bergman

Show description

Read or Download Activation and Functionalization of C—H Bonds PDF

Similar organic books

Stanley R. Sandler, Wolf Karo, JoAnne Bonesteel, Eli M.'s Polymer Synthesis and Characterization: A Laboratory Manual PDF

This laboratory handbook presents a accomplished advent to an array of vital suggestions for polymer synthesis and characterization. The experiments are designed to be accomplished in a single laboratory interval utilizing restricted amounts of fabrics to lessen the prices and disposal difficulties, and have been reviewed for lecture room use at Polytechnic collage.

Modern Gold Catalyzed Synthesis by A. Stephen K. Hashmi, F. Dean Toste PDF

With its extraordinary positive aspects, gold has ended in thoroughly new response kinds in recent times, which in flip have strongly encouraged either natural catalysis and fabric technology. different fields the place an important volume of latest effects has been got comprise nanotechnology, self assembly/supramolecular platforms and biochemical/medicinal chemistry.

New PDF release: New Theoretical Concepts for Understanding Organic Reactions

Those who attended the NATO complex learn Institute (ASI) entitled NEW THEORETICAL options FOR knowing natural REAC­ TIONS held at Sant Feliu de Gufxols at the Costa Brava of Spain had a distinct adventure. they've got obvious the evolution of the sphere from qualitative arguments during the new release of power strength Surfaces (PES) to using PES in molecular dynamics.

Applications of domino transformations in organic synthesis - download pdf or read online

The quick speed of evolution in domino, or cascade-based ameliorations has revolutionized the perform of chemical synthesis for the production of average items, designed molecules, and prescription drugs. "Science of Synthesis: purposes of Domino changes in natural Synthesis" explores the subject completely and systematically, serving because the foundation for useful functions and destiny study.

Additional info for Activation and Functionalization of C—H Bonds

Example text

McNamara, B. ; Kotz, K. ; Yeston, J. ; Bergman, R. ; Harris, C. B. Science 1997, 278, 260. (c) McNamara, Β. ; Yeston, J. ; Bergman, R. ; Moore, C. B. J. Am. Chem. Soc. 1999,121,6437. (d) Asplund, M . ; Snee, P. ; Yeston, J. ; Wilkens, M . ; Payne, C. ; Kotz, K. ; Bergman, R. ; Harris, C. B. J. Am. Chem. Soc. 2002, 124, 10605. 66. Halpern, J. Inorg. Chim. Acta. 1985,100,41. 67. Rest, A. ;Graham, W. A. ; Hoyano, J. ; McMaster, A. D. J. ,Chem. Commun. 1984, 624. 68. ; Hoffmann, R. J. Am. Chem. Soc.

Soc. 1988, 110, 8731. 149. Walsh, P. ; Hollander, F. ; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729. 150. ; Pamplin, C. ; Patrick, B. ; Bau, R. J. Am. Chem. Soc. 2003, 125, 7035. 151. (a) Del Rossi, K. ; Wayland, Β. B. J. Am. Chem. Soc. 1985, 107, 7941. (b) Del Rossi, K. ; Wayland, Β. B. Chem. Comm. 1986, 1653. (c) Sherry, A. ; Wayland, Β. B. J. Am. Chem. Soc. 1990, 112, 1259. (d) Wayland, B. ; Sherry, A. E. J. Am. Chem. Soc. 1991, 113, 5305. 152. ; Wayland, Β. B. J. Am. Chem. Soc. 1994, 116, 7897.

G. eq 30) (128,129). Quantum yields and turnovers were much higher than were obtained for carbonylation. This reaction might be considered the first example of highly efficient alkane functionalization catalyzed via an organometallic route. ch001 2 6 3 2 (30) Mechanistic studies of this system led Maguire and Goldman to the conclusion that the role of the photon was expulsion of C O (and not photoelimination of H from an intermediate). The resulting Rh(PMe ) Cl fragment then reacts thermochemically with alkane to give H Rh(PMe ) Cl; C O then displaces H to complete the catalytic cycle (129).

Download PDF sample

Activation and Functionalization of C—H Bonds by Karen I. Goldberg and Alan S. Goldman (Eds.)


by Jason
4.5

Rated 4.03 of 5 – based on 15 votes